Products
3-Chloro-2-methylaniline
Another name：3-chloro-o-toluidin; Benzenamine, 3-chloro-2-methyl-; scarlettrbase; 3-Chlor-2-toluidin;
CasNo: 87-60-5 Purity： >99% Molecular Structure： C7H8ClN
3-Chloro-2-methylaniline Basic Product Information
| Product Name | 3-Chloro-2-methylaniline | CAS | 87-60-5 |
| Synonyms | 3-chloro-o-toluidin; Benzenamine, 3-chloro-2-methyl-; scarlettrbase; 3-Chlor-2-toluidin; |
Molecular Formula | C7H8ClN |
| EINECS Number | 201-756-6 | Molecular Structure | |
| Appearance | Brown-red liquid |
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| Purity | >99% | ||
| Supply Ability |
100T / Per Month |
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3-Chloro-2-methylaniline Appearance/Package/Shipping/Storage
Package
10-30T/Iso-tank , 200L/Iron Drum;
Storage condition
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances；
3-Chloro-2-methylaniline Application
It is an important raw material for synthetic dyes and pesticides and can synthesize dye DB-50 and produce paddy field herbicides such as quick-kill barnyard grass;
3-Chloro-2-methylaniline literature
NaI/PPh3-Mediated Photochemical Reduction and Amination of Nitroarenes
Qu, Zhonghua,Chen, Xing,Zhong, Shuai,Deng, Guo-Jun,Huang, Huawen
supporting information, p. 5349 - 5353 (2021/07/21)
A mild transition-metal- and photosensitizer-free photoredox system based on the combination of NaI and PPh3 was found to enable highly selective reduction of nitroarenes. This protocol tolerates a broad range of reducible functional groups such as halogen (Cl, Br, and even I), aldehyde, ketone, carboxyl, and cyano. Moreover, the photoredox catalysis with NaI and stoichiometric PPh3 provides also an alternative entry to Cadogan-type reductive amination when o-nitrobiarenes were used.
Highly Efficient and Chemoselective Hydrogenation of Nitro Compounds into Amines by Nitrogen-Doped Porous Carbon-Supported Co/Ni Bimetallic Nanoparticles
Shen, Zeyu,Hong, Lirui,Zheng, Baishu,Wang, Guanyu,Zhang, Beibei,Wang, Zhaoxu,Zhan, Feiyang,Shen, Shaohua,Yun, Ruirui
supporting information, p. 16834 - 16839 (2021/11/17)
A novel Co/Ni bimetallic nanoparticle supported by nitrogen-doped porous carbon (NPC), Co5/Ni@NPC-700, exhibits high conversion, chemoselectivity, and recyclability in the hydrogenation of 16 different nitro compounds into desired amines with hydrazine hydrate under mild conditions. The synergistic effects of Co/Ni bimetal nanoparticles and the NPC-supported porous honeycomb structure with more accessible active sites may be responsible for the high catalytic hydrogenation performance.
A Pod-like Core-Shell Catalyst with High Reduction Performance Under Mild Conditions
Du, Liting,He, Lei,Li, Tuanhui,Luo, Shizhou,Xu, Fagong,Yun, Ruirui,Zhan, Feiyang,Zhang, Beibei,Zheng, Baishu
, (2022/01/11)
Recent years, tubular structure as the carrier loading nanoparticles has been reported more and more frequently which is synthesized by pyrolysis polyhedral MOFs. However, the construct mechanism has not been referred. Herein, a tubular structure has been designed by calcining modified ZIF-8 under different temperature to reveal the formation process of tubular carbon from the polyhedron. As a result, a pod-like core-shell catalyst of Fe/Fe3C-900 has been obtained and exhibits a high activity and excellent substituent tolerance for the reduction of nitro groups under mild conditions.
Copper(II) complex with oxazoline ligand: Synthesis, structures and catalytic activity for nitro compounds reduction
Du, Jun,Gao, Li-Li,Jia, Wei-Guo,Li, Mei,Zhi, Xue-Ting
, (2020/05/14)
The Cu(II) complexes bearing bisoxazolines, tridentate pincer pybox and terpyridine ligands have been synthesized and fully characterized. The molecular structures of copper complexes 1a and 1c were confirmed by single-crystal X-ray diffraction methods. These copper complexes highly catalyzed nitro compounds reduction to aniline and its derivatives in the presence of NaBH4 reducing agent in water solvent. The complex 1e was an efficient catalyst toward nitro compounds reduction with wide functional group substrate scope and aliphatic nitro compounds.
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